化合物简介
(4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, is a privileged ligand analogue of TADDOLs. It can be broadly used in asymmetric synthesis. It is also shown that the titanium TADDOLate catalysts have broad application towards carbonyl addition and cycloaddition.
基本信息
中文名称
(-)-2,3-O-异亚丙基-1,1,4,4-四(2-萘)-l-异赤醇
英文名称
[5-(hydroxymethyl)-2,2-dimethyl-4,5-dinaphthalen-2-yl-1,3-dioxolan-4-yl]-dinaphthalen-2-ylmethanol
中文别名
(4R,5R)-2,2-二甲基-Α,Α,Α′,Α′-四(2-萘基)二氧戊环-4,5-二甲醇、(4R,5R)-2,2-二甲基-Α,Α,Α`,Α`-四(2-萘基)-1,3-二氧戊烷-4,5-二甲醇
英文别名
(4R,5R)-2,2-dimethyltetra(2-naphthyl)-TADDOL、1,3-Dioxolane-4,5-dimethanol,2,2-dimethyl-a,a,a\',a\'-tetra-2-naphthalenyl-,(4R,5R)-(9CI)、(R)-2-naphthyl-taddol、(4R,5R)-2,2-Dimethyl-a,a,a\',a\'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol、1,3-Dioxolane-4,5-dimethanol,2,2-dimethyl-a,a,a\',a\'-tetra-2-naphthalenyl-,(4R-trans)、[(4R,5R)-2,2-dimethyl-1,3-dioxolan-4,5-diyl]bis(dinaphthalen-2-ylmethanol)、1,3-Dioxolane-4,5-dimethanol,2,2-dimethyl-a4,a4,a5,a5-tetra-2-naphthalenyl-,(4R,5R)
CAS号
137365-09-4
分子式
C47H38O4
分子量
666.802
精确质量
666.277
PSA
58.92
LOGP
9.9915
物化性质
密度
1.269g/cm3
熔点
213-216ºC(lit.)
折射率
1.718
储存条件
2-8ºC
合成路线
