合成路线
(3aS,12aS)-2,2-dimethyl-3a,5,6,12a-tetrahydro-[1,3]dioxolo[4',5':4,5]cyclopenta[1,2-b][1,3]dioxolo[5',4':4,5]benzo[1,2-d]azepin-12(4H)-one
CAS号：910138-79-3
英文名：(3aS,12aS)-2,2-dimethyl-3a,5,6,12a-tetrahydro-[1,3]dioxolo[4',5':4,5]cyclopenta[1,2-b][1,3]dioxolo[5',4':4,5]benzo[1,2-d]azepin-12(4H)-one
分子式：C17H17NO5
分子量：315.321
上游原料
(+)-6-chloro-2,2-dimethyl-5-(phenylselenyl)tetrahydrocyclopenta[1,3]dioxol-4-ol
6-chloro-4-hydroxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxol-4-ol
4-(tert-butyl-dimethyl-silanyloxymethyl)-6-chloro-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxol-4-ol
4-(tert-Butyl-dimethyl-silanyloxymethyl)-6-chloro-2,2-dimethyl-5-phenylselanyl-tetrahydro-cyclopenta[1,3]dioxol-4-ol
下游产品
bis(de-methyl)-deoxyharringtonine
benzyl ((2S,3S,3aR)-2,3-dihydroxy-2,3,5,6,8,9-hexahydro-4H-[1,3]dioxolo[4',5':4,5]benzo[1,2-d]cyclopenta[b]pyrrolo[1,2-a]azepin-1-yl) carbonate
benzyl (3aS,15aS)-2,2-dimethyl-15-oxo-3a,4,5,6,8,9,15,15a-octahydro-7H-[1,3]dioxolo[4',5':4,5]benzo[1,2-d][1,3]dioxolo[5',4':3,4]cyclopenta[1,2-f]azecine-7-carboxylate
三尖杉碱
(1S,3aR,14bS)-2-methoxy-1,5,6,8,9,14b-hexahydro-4H-[1,3]dioxolo[4',5':4,5]benzo[1,2-d]cyclopenta[b]pyrrolo[1,2-a]azepin-1-yl (R)-4-oxo-2-propyloxetane-2-carboxylate
(R,E)-2-(4-(benzyloxy)-4-methylpent-2-enyl)-4-oxooxetane-2-cephalotaxyl carboxylate
