[(1S,2S,5R,8aS)-5-(3-Benzyloxy-propyl)-2-hydroxymethyl-5-methyl-1-(2-triisopropylsilanyloxy-ethyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-methanol

[(1S,2S,5R,8aS)-5-(3-Benzyloxy-propyl)-2-hydroxymethyl-5-methyl-1-(2-triisopropylsilanyloxy-ethyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-methanol

CAS号：201209-97-4

英文名：[(1S,2S,5R,8aS)-5-(3-Benzyloxy-propyl)-2-hydroxymethyl-5-methyl-1-(2-triisopropylsilanyloxy-ethyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-methanol

分子式：C34H58O4Si

分子量：558.907

合成路线

5-(triisopropylsilyloxy)pent-2-ynoic acid ethyl ester

5-(triisopropylsilyloxy)pent-2-ynoic acid ethyl ester

[(1S,2S,5R,8aS)-5-(3-Benzyloxy-propyl)-2-hydroxymethyl-5-methyl-1-(2-triisopropylsilanyloxy-ethyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-methanol

[(1S,2S,5R,8aS)-5-(3-Benzyloxy-propyl)-2-hydroxymethyl-5-methyl-1-(2-triisopropylsilanyloxy-ethyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-methanol

(+)-2-(3-benzyloxypropyl)-2-methylcyclohexanone

(+)-2-(3-benzyloxypropyl)-2-methylcyclohexanone

[(1S,2S,5R,8aS)-5-(3-Benzyloxy-propyl)-2-hydroxymethyl-5-methyl-1-(2-triisopropylsilanyloxy-ethyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-methanol

[(1S,2S,5R,8aS)-5-(3-Benzyloxy-propyl)-2-hydroxymethyl-5-methyl-1-(2-triisopropylsilanyloxy-ethyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-methanol

上游原料

(+)-2-(3-benzyloxypropyl)-2-methylcyclohexanone 5-(triisopropylsilyloxy)pent-2-ynoic acid ethyl ester

下游产品

Triisopropyl-{2-[(1S,2S,5R,8aR)-1,2,5-trimethyl-5-(4-methyl-pent-4-enyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-ethoxy}-silane (R)-1-(5-Triisopropylsilanyloxy-furan-3-yl)-2-[(1S,2S,5R,8aR)-1,2,5-trimethyl-5-(4-methyl-pent-4-enyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-ethanol [(1S,2S,5R,8aR)-1,2,5-Trimethyl-5-(4-methyl-pent-4-enyl)-1,2,3,5,6,7,8,8a-octahydro-naphthalen-1-yl]-acetaldehyde