(1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyloxy-1-methyl-7-oxabicyclo[4.1.0]heptane

(1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyloxy-1-methyl-7-oxabicyclo[4.1.0]heptane

CAS号：132870-50-9

英文名：(1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyloxy-1-methyl-7-oxabicyclo[4.1.0]heptane

分子式：C15H28O4Si

分子量：300.466

合成路线

p-Menth-8-en-2-one, 1,6-epoxy-, (1R,4R,6R)-(-)-

p-Menth-8-en-2-one, 1,6-epoxy-, (1R,4R,6R)-(-)-

(1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyloxy-1-methyl-7-oxabicyclo[4.1.0]heptane

(1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyloxy-1-methyl-7-oxabicyclo[4.1.0]heptane

左旋香芹酮

左旋香芹酮

(1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyloxy-1-methyl-7-oxabicyclo[4.1.0]heptane

(1S,2S,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-acetyloxy-1-methyl-7-oxabicyclo[4.1.0]heptane

上游原料

p-Menth-8-en-2-one, 1,6-epoxy-, (1R,4R,6R)-(-)- 左旋香芹酮

下游产品

(1S,2R,3R,5S)-3-benzyloxy-5-(tert-butyldimethylsilyloxy)-2-hydroxymethyl-cyclohexanol (1R,2S,4R,6R)-2,4-二(叔-丁基二甲基硅烷基氧基)-1-甲基-环己烷1,2-环氧化物