(4R,5S)-3-[(2R,3S,4S,5S,6S,7R)-6-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-((Z)-3-iodo-2-methyl-allyl)-8-(4-methoxy-benzyloxy)-2,5,7-trimethyl-octanoyl]-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-[(2R,3S,4S,5S,6S,7R)-6-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-((Z)-3-iodo-2-methyl-allyl)-8-(4-methoxy-benzyloxy)-2,5,7-trimethyl-octanoyl]-4-methyl-5-phenyl-oxazolidin-2-one

CAS号：1026848-01-0

英文名：(4R,5S)-3-[(2R,3S,4S,5S,6S,7R)-6-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-((Z)-3-iodo-2-methyl-allyl)-8-(4-methoxy-benzyloxy)-2,5,7-trimethyl-octanoyl]-4-methyl-5-phenyl-oxazolidin-2-one

分子式：C39H58INO7Si

分子量：807.87

合成路线

((2R,3S,4S)-3-Benzyloxy-2,4-dimethyl-hex-5-enyloxy)-tert-butyl-diphenyl-silane

((2R,3S,4S)-3-Benzyloxy-2,4-dimethyl-hex-5-enyloxy)-tert-butyl-diphenyl-silane

(4R,5S)-3-[(2R,3S,4S,5S,6S,7R)-6-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-((Z)-3-iodo-2-methyl-allyl)-8-(4-methoxy-benzyloxy)-2,5,7-trimethyl-octanoyl]-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-[(2R,3S,4S,5S,6S,7R)-6-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-((Z)-3-iodo-2-methyl-allyl)-8-(4-methoxy-benzyloxy)-2,5,7-trimethyl-octanoyl]-4-methyl-5-phenyl-oxazolidin-2-one

(3S,4S,5S)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-3-((Z)-3-iodo-2-methyl-allyl)-4-methyl-dihydro-furan-2-one

(3S,4S,5S)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-3-((Z)-3-iodo-2-methyl-allyl)-4-methyl-dihydro-furan-2-one

(4R,5S)-3-[(2R,3S,4S,5S,6S,7R)-6-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-((Z)-3-iodo-2-methyl-allyl)-8-(4-methoxy-benzyloxy)-2,5,7-trimethyl-octanoyl]-4-methyl-5-phenyl-oxazolidin-2-one

(4R,5S)-3-[(2R,3S,4S,5S,6S,7R)-6-(tert-Butyl-dimethyl-silanyloxy)-3-hydroxy-4-((Z)-3-iodo-2-methyl-allyl)-8-(4-methoxy-benzyloxy)-2,5,7-trimethyl-octanoyl]-4-methyl-5-phenyl-oxazolidin-2-one

上游原料

((2R,3S,4S)-3-Benzyloxy-2,4-dimethyl-hex-5-enyloxy)-tert-butyl-diphenyl-silane (3S,4S,5S)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-3-((Z)-3-iodo-2-methyl-allyl)-4-methyl-dihydro-furan-2-one

下游产品

(E)-(4S,5R,6S,7S,8S,9R)-8-(tert-Butyl-dimethyl-silanyloxy)-6-((Z)-3-iodo-2-methyl-allyl)-10-(4-methoxy-benzyloxy)-2,4,7,9-tetramethyl-5-triethylsilanyloxy-dec-2-en-1-ol